Volume 21
Main Index

Issue 01

Masthead DOI: 10.1021/ar00145a700

High transition temperature inorganic oxide superconductors: synthesis, crystal structure, electrical properties, and electronic structure Jack M. Williams, Mark A. Beno, K. Douglas Carlson, Urs Geiser, H. C. Ivy Kao, Aravinda M. Kini, Leigh C. Porter, Arthur J. Schultz, Robert J. Thorn, pp 1–7 DOI: 10.1021/ar00145a001

Physical properties of the quaternary yttrium barium copper oxide superconductor (YBa2Cu3O7) Gary F. Holland, Angelica M. Stacy pp 8–15 DOI: 10.1021/ar00145a002

The reaction coordinate and its limitations: an experimental perspective Cornelius E. Klots pp 16–21 DOI: 10.1021/ar00145a003

Photochemistry of organic reaction intermediates: novel reaction paths induced by two-photon laser excitation J. C. Scaiano, L. J. Johnston, W. G. McGimpsey, D. Weir pp 22–29 DOI: 10.1021/ar00145a004

The catalytic mechanism of carbonic anhydrase: implications of a rate-limiting protolysis of water David N. Silverman, Sven Lindskog pp 30–36 DOI: 10.1021/ar00145a005

The two-dimensional NMR spectroscopy of macromolecules Frank A. Bovey, Peter A. Mirau pp 37–43 DOI: 10.1021/ar00145a006

Issue 02

Masthead DOI: 10.1021/ar00146a700

Olefin synthesis via organometallic coupling reactions of enol triflates William J. Scott, John E. McMurry pp 47–54 DOI: 10.1021/ar00146a001

Flash photolysis electron spin resonance Keith A. McLauchlan, D. G. Stevens pp 54–59 DOI: 10.1021/ar00146a002

Modifications of transition-metal reaction patterns through the manipulation of superexchange couplings John F. Endicott pp 59–66 DOI: 10.1021/ar00146a003

Intercalation and binding of carcinogenic hydrocarbon metabolites to nucleic acids Ronald G. Harvey, Nicholas E. Geacintov pp 66–73 DOI: 10.1021/ar00146a004

Probing radicals with alcohol thermolysis and molecular mechanics John S. Lomas pp 73–80 DOI: 10.1021/ar00146a005

The quest for terminal phosphinidene complexes Alan H. Cowley, Andrew R. Barron pp 81–87 DOI: 10.1021/ar00146a006

A "new" general mechanism of ammonia synthesis and decomposition on transition metals Kenzi Tamaru pp 88–94 DOI: 10.1021/ar00146a007

Ultraviolet and infrared linear dichroism: polarized light as a probe of molecular and electronic structure [Erratum to document cited in CA106(22):184975h] Josef Michl, Erik W. Thulstrup pp 94–94 DOI: 10.1021/ar00146a008

Issue 03

Masthead DOI: 10.1021/ar00147a700

Sign variation in the magnetic circular dichroism spectra of .pi.-substituted porphyrins Robert A. Goldbeck pp 95–101 DOI: 10.1021/ar00147a001

Mechanism of oxygen activation by pteridine-dependent monooxygenases Thomas A. Dix, Stephen J. Benkovic pp 101–107 DOI: 10.1021/ar00147a002

EPR studies of long-range intramolecular electron-electron exchange interaction Gareth R. Eaton, Sandra S. Eaton pp 107–113 DOI: 10.1021/ar00147a003

Molecular ferromagnets Joel S. Miller, Arthur J. Epstein, William M. Reiff pp 114–120 DOI: 10.1021/ar00147a004

Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals Kubas Gregory J. pp 120–128 DOI: 10.1021/ar00147a005

Time-resolved studies of solvation in polar media John D. Simon pp 128–134 DOI: 10.1021/ar00147a006

Issue 04

Masthead DOI: 10.1021/ar00148a700

Generation of simple enols in solution Brian Capon, Bo Zhang Guo, Fu Chiu Kwok, Arup K. Siddhanta, Cesar Zucco pp 135–140 DOI: 10.1021/ar00148a001

Crown thio ether chemistry Stephen R. Cooper pp 141–146 DOI: 10.1021/ar00148a002

Free inorganic, organic, and organometallic ions by treatment of their lithium salts with 12-crown-4 Philip P. Power pp 147–153 DOI: 10.1021/ar00148a003

Cyclometalation chemistry of aryl oxide ligation Ian P. Rothwell pp 153–159 DOI: 10.1021/ar00148a004

Long-distance electron transfer in proteins and model systems George McLendon pp 160–167 DOI: 10.1021/ar00148a005

Solution thermodynamics for liquid metals Wayne J. Howell, Charles A. Eckert pp 168–174 DOI: 10.1021/ar00148a006

Stereochemical consequences of dynamic gearing Hiizu Iwamura, Kurt Mislow pp 175–182 DOI: 10.1021/ar00148a007

Issue 05

Masthead DOI: 10.1021/ar00149a700

Chemisorption theory: in search of the elephant Evgeny Shustorovich pp 183–189 DOI: 10.1021/ar00149a001

Topological control of the structures of molecules and solids Jeremy K. Burdett pp 189–194 DOI: 10.1021/ar00149a002

Dynamic solvent effects on polar and nonpolar isomerizations Paul F. Barbara, Wlodzimierz Jarzeba pp 195–199 DOI: 10.1021/ar00149a003

Characteristics in the reactions of allylsilanes and their applications to versatile synthetic equivalents Akira Hosomi pp 200–206 DOI: 10.1021/ar00149a004

A critical evaluation of studies employing alkenyl halide "mechanistic probes" as indicators of single-electron-transfer processes Martin Newcomb, Dennis P. Curran pp 206–214 DOI: 10.1021/ar00149a005

Issue 06

Masthead DOI: 10.1021/ar00150a700

Radiolytic approach to gas-phase ion chemistry Fulvio Cacace pp 215–222 DOI: 10.1021/ar00150a001

X-ray diffraction in the multimegabar regime using synchrotron radiation at the Cornell High-Energy Synchrotron Source (CHESS) Arthur L. Ruoff pp 223–228 DOI: 10.1021/ar00150a002

Nucleophilic addition reactions with cationic iron .pi.-alkyne and related complexes Daniel L. Reger pp 229–235 DOI: 10.1021/ar00150a003

Atom-transfer reactions of aromatic carbenes Matthew S. Platz pp 236–242 DOI: 10.1021/ar00150a004

.pi.-Electrons in three dimensiona Robert C. Haddon pp 243–249 DOI: 10.1021/ar00150a005

Nickel dibromide: a magnetic detective story Peter Day pp 250–254 DOI: 10.1021/ar00150a006

Issue 07

Masthead DOI: 10.1021/ar00151a700

Microemulsions D. Langevin pp 255–260 DOI: 10.1021/ar00151a001

Magnesium anthracene systems and their application in synthesis and catalysis Borislav Bogdanovic pp 261–267 DOI: 10.1021/ar00151a002

Dynamical structure analysis of crystalline-state racemization Yuji Ohashi pp 268–274 DOI: 10.1021/ar00151a003

Photophysical and photochemical processes on clay surfaces J. K. Thomas pp 275–280 DOI: 10.1021/ar00151a004

Extraordinary behavior in the structural properties of colloidal macroions in deionized suspension and the importance of the Debye screening length Tsuneo Okubo pp 281–286 DOI: 10.1021/ar00151a005

Issue 08

Masthead DOI: 10.1021/ar00152a700

The development of a simple general procedure for synthesis of pure enantiomers via chiral organoboranes Herbert C. Brown, Bakthan Singaram pp 287–293 DOI: 10.1021/ar00152a001

Asymmetric synthesis with boronic esters Donald S. Matteson pp 294–300 DOI: 10.1021/ar00152a002

Photochemistry and photophysics within cyclodextrin cavities V. Ramamurthy, David F. Eaton pp 300–306 DOI: 10.1021/ar00152a003

Elemental fluorine as a legitimate reagent for selective fluorination of organic compounds Shlomo Rozen pp 307–312 DOI: 10.1021/ar00152a004

Synthetic methodology based upon N-sulfinyl dienophile [4 + 2]-cycloaddition reactions Steven M. Weinreb pp 313–318 DOI: 10.1021/ar00152a005

Issue 09

Masthead DOI: 10.1021/ar00153a700

Application of size exclusion chromatography coupled with element-specific detection to the study of heavy crude oil and residua processing John G. Reynolds, Wilton R. Biggs pp 319–326 DOI: 10.1021/ar00153a001

How bromate oscillators are controlled Peter Ruoff, Margit Varga, Endre Koros pp 326–332 DOI: 10.1021/ar00153a002

Structural basis of the action of thermolysin and related zinc peptidases Brian W. Matthews pp 333–340 DOI: 10.1021/ar00153a003

Photoinitiated reactions in weakly bonded complexes C. Wittig, S. Sharpe, R. A. Beaudet pp 341–347 DOI: 10.1021/ar00153a004

Significance of slow-binding enzyme inhibition and its relationship to reaction-intermediate analogs John V. Schloss pp 348–353 DOI: 10.1021/ar00153a005

Issue 10

Masthead DOI: 10.1021/ar00154a700

Intermolecular electrical interaction: a key ingredient in hydrogen bonding Clifford E. Dykstra pp 355–361 DOI: 10.1021/ar00154a001

Hydrophobic-lipophilic interactions. Aggregation and self-coiling of organic molecules Xikui Jiang pp 362–367 DOI: 10.1021/ar00154a002

Nerve agent stereoisomers: analysis, isolation and toxicology H. P. Benschop, L. P. A. De Jong pp 368–374 DOI: 10.1021/ar00154a003

Transformations of carbon monoxide and related ligands on metal ensembles Duward F. Shriver, Michael J. Sailor pp 374–379 DOI: 10.1021/ar00154a004

Photophysics and intramolecular photochemistry of thiones in solution R. P. Steer, V. Ramamurthy pp 380–386 DOI: 10.1021/ar00154a005

Issue 11

Masthead DOI: 10.1021/ar00155a700

Heterogeneous catalysis of the hydrodesulfurization of thiophenes in petroleum: an organometallic perspective of the mechanism Robert J. Angelici pp 387–394 DOI: 10.1021/ar00155a001

Deduction of reaction mechanisms for surface processes: desulfurization of organic sulfides and thiols on molybdenum(110) Cynthia M. Friend, Jeffrey T. Roberts pp 394–400 DOI: 10.1021/ar00155a002

In search of carbene ion radicals in solution: reaction pathways and reactivity of ion radicals of diazo compounds Donald Bethell, Vernon D. Parker pp 400–407 DOI: 10.1021/ar00155a003

Direct electrochemistry of redox proteins Fraser A. Armstrong, H. Allen O. Hill, Nicholas J. Walton pp 407–413 DOI: 10.1021/ar00155a004

Single-electron transfer, a major reaction pathway in organic chemistry. An answer to recent criticisms E. C. Ashby pp 414–421 DOI: 10.1021/ar00155a005

Organometallic chemistry of electrophilic transition and lanthanide metal ions. The dominant pathways for reactions involving carbon-carbon double and single bonds and carbon-hydrogen bonds Ayusman Sen pp 421–428 DOI: 10.1021/ar00155a006

Aspects of intermediacy of carbalkoxymetal complexes in carbon monoxide reactions David Milstein pp 428–434 DOI: 10.1021/ar00155a007

Issue 12

Masthead DOI: 10.1021/ar00156a700

Membrane-impermeant crosslinking reagents: probes of the structure and dynamics of membrane proteins James V. Staros pp 435–441 DOI: 10.1021/ar00156a001

Sterically crowded stable simple enols Zvi Rappoport, Silvio E. Biali pp 442–449 DOI: 10.1021/ar00156a002

Transition-state structures in enzyme-catalyzed decarboxylations Marion H. O'Leary pp 450–455 DOI: 10.1021/ar00156a003

Equilibrium acidities in dimethyl sulfoxide solution Frederick G. Bordwell pp 456–463 DOI: 10.1021/ar00156a004

Structural and solvent effects evaluated from acidities measured in dimethyl sulfoxide and in the gas phase Robert W. Taft, Frederick G. Bordwell pp 463–469 DOI: 10.1021/ar00156a005

Hydroxide ion: an effective one-electron reducing agent? Donald T. Sawyer, Julian L. Roberts Jr. pp 469–476 DOI: 10.1021/ar00156a006